Posted: December 3rd, 2014
Identify the mechanisms of the processes observed in the following experiments, and write
electrochemical (with Eo’ specified)
Due Nov. 26
th
, 2014
1)
Identify the mechanisms of the processes observed in the following experiments, and write
electrochemical (with E
o
’ specified) and chemical equations to describe these processes. You may use
symbols (e.g. X) to indicate u
nknown products, but suggest identities for such species if you can.
a.
Cyclic voltammograms of the redox enzyme glucose oxidase in the absence (a) and presence (b)
of glucose
b.
Cyclic voltammograms of (a) 4
–
chlorobenzonitrile, (b) benzo
nitrile at a Pt
–
electrode in
DMF/Et
4
NClO
4
(0.1 mol dm
–
3
). Potential scan rate 0.08
V
.
s
–
1
C
N
C
N
Cl
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